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Formation of a Sterically Crowded 1,6,6αλ⁴-Triselenapentalene and 4H-Selenopyran-4-selones Fused with Two Bornane Skeletons Through the Reaction of d-Camphor p-Toluenesulfonylhydrazone With a Base and Elemental Selenium
https://iwate-u.repo.nii.ac.jp/records/14924
https://iwate-u.repo.nii.ac.jp/records/14924836923e8-5603-4ca2-8c90-a3431c68f004
名前 / ファイル | ライセンス | アクション |
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npc-v15n2p1-13 (944.1 kB)
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2020-03-26 | |||||
タイトル | ||||||
タイトル | Formation of a Sterically Crowded 1,6,6αλ⁴-Triselenapentalene and 4H-Selenopyran-4-selones Fused with Two Bornane Skeletons Through the Reaction of d-Camphor p-Toluenesulfonylhydrazone With a Base and Elemental Selenium | |||||
言語 | ||||||
言語 | eng | |||||
キーワード | ||||||
言語 | en | |||||
主題Scheme | Other | |||||
主題 | d-camphorp-toluenesulfonylhydrazone | |||||
キーワード | ||||||
言語 | en | |||||
主題Scheme | Other | |||||
主題 | 1,6,6αλ⁴-triselenapentalene | |||||
キーワード | ||||||
言語 | en | |||||
主題Scheme | Other | |||||
主題 | 4H-selenopyran-4-selone | |||||
キーワード | ||||||
言語 | en | |||||
主題Scheme | Other | |||||
主題 | steric protection | |||||
キーワード | ||||||
言語 | en | |||||
主題Scheme | Other | |||||
主題 | 1,2-diselenole | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | journal article | |||||
著者 |
SHIMADA, Kazuaki
× SHIMADA, Kazuaki× AOYAGI, Shigenobu× TAKIKAWA, Yuji |
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著者(機関) | ||||||
Department of Chemistry and Biosciences, Faculty of Science and Engineering, Iwate University | ||||||
著者(機関) | ||||||
Department of Chemistry and Biosciences, Faculty of Science and Engineering, Iwate University | ||||||
著者(機関) | ||||||
Department of Chemistry and Biosciences, Faculty of Science and Engineering, Iwate University | ||||||
登録日 | ||||||
日付 | 2020-03-26 | |||||
書誌情報 |
Natural Product Communications 巻 15, 号 2, p. 1-13, 発行日 2020-02-01 |
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ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 1934578X | |||||
ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 15559475 | |||||
Abstract | ||||||
内容記述タイプ | Other | |||||
内容記述 | Reaction of d-camphor p-toluenesulfonylhydrazone with t-butoxide and elemental selenium in dimethylformamide at an elevated temperature afforded a stable compound having a unique 1,6,6αλ⁴-triselenapentalene ring and 4H-selenopyran-4-selones along with dialkenyl diselenide, dibornylenes, and 1,2,5-triselenepin, and the structural confirmation of these products were carried out by X-ray crystallographic analysis. The sterically crowded 1,6,6aλ⁴-triselenapentalene ring fused with two bornane sleketons was stable enough under aerobic exposure and was inactive toward sodium borohydride reduction but was converted into 1,2-diselenole derivative through m-chloroperbenzoic acid oxidation. | |||||
出版者 | ||||||
出版者 | SAGE | |||||
権利 | ||||||
権利情報 | ©The Author(s) 2019 | |||||
権利 | ||||||
権利情報 | Creative Commons Non Commercial CC BY-NC: This article is distributed under the terms of the Creative Commons Attribution-NonCommercial 4.0 License (http:// creativecommons. org/ licenses/ by- nc/ 4. 0/) which permits non-commercial use, reproduction and distribution of the work without further permission provided the original work is attributed as specified on the SAGE and Open Access pages (https:// us. sagepub. com/ en- us/ nam/ open- access- at- sage). | |||||
DOI | ||||||
関連タイプ | isIdenticalTo | |||||
識別子タイプ | DOI | |||||
関連識別子 | info:doi/10.1177/1934578X19896686 | |||||
著者版フラグ | ||||||
出版タイプ | VoR | |||||
出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 |