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Vinylene-Bridged CyclicDipyrrin and BODIPY Trimers
https://iwate-u.repo.nii.ac.jp/records/15501
https://iwate-u.repo.nii.ac.jp/records/15501aac4150a-813e-4665-bc68-c2077efc3eac
名前 / ファイル | ライセンス | アクション |
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ijms-v21n21p8041 (4.7 MB)
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2022-01-05 | |||||
タイトル | ||||||
タイトル | Vinylene-Bridged CyclicDipyrrin and BODIPY Trimers | |||||
言語 | ||||||
言語 | eng | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | expanded porphyrin | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | boron complex | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | molecular configuration | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | journal article | |||||
著者 |
XUE, Songlin
× XUE, Songlin× KUZUHARA, Daiki× ARATANI, Naoki× YAMADA, Hiroko |
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著者(機関) | ||||||
School of Chemistry and Chemical Engineering, Jiangsu University | ||||||
著者(機関) | ||||||
Faculty of Science and Engineering, Iwate University | ||||||
著者(機関) | ||||||
Division of Materials Science, Nara Institute of Science and Technology | ||||||
著者(機関) | ||||||
Division of Materials Science, Nara Institute of Science and Technology | ||||||
登録日 | ||||||
日付 | 2022-01-05 | |||||
書誌情報 |
International Journal of Molecular Sciences 巻 21, 号 21, p. 8041, 発行日 2020-10-28 |
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ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 14220067 | |||||
抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | Vinylene-bridged cyclic boron–difluoride complex of dipyrrin (BODIPY) trimers were successfully prepared from expanded dimethyl-vinylene bridged hexaphyrin(2.1.2.1.2.1) Me-Hex that has the structure of alternate dipyrrins and vinylene bridges. The hexaphyrin(2.1.2.1.2.1) Me-Hex can coordinate with boron ions to a_ord five kinds of cyclic BODIPYs given by step-by-step boron complexations. Crystal structures of all cyclic BODIPYs except for 3BF2-Me-Hex(b) formed non-planar structures. The theoretical calculation predicted that mono-/bis-boron cyclic BODIPYs show the intramolecular charge transfer (ICT) characteristics, whereas tri-boron cyclic BODIPYs have no ICT characteristics. Reflecting these electronic properties, tri-boron cyclic BODIPYs exhibit weak fluorescence in the red region, but mono-/bis-boron cyclic BODIPYs exhibit no emission. Vinylene bridged cyclic dipyrrin trimer Me-Hex is the novel porphyrinoid ligand allowed to control the boron coordination under di_erent reaction conditions to form various boron complexes. | |||||
抄録(URL) | ||||||
Vinylene-Bridged Cyclic Dipyrrin and BODIPY Trimers | ||||||
https://www.mdpi.com/1422-0067/21/21/8041 | ||||||
出版者 | ||||||
出版者 | MDPI | |||||
権利 | ||||||
権利情報 | © 2020 by the authors. Licensee MDPI, Basel, Switzerland. | |||||
権利URI | ||||||
権利情報 | http://creativecommons.org/licenses/by/4.0/ | |||||
NCID | ||||||
収録物識別子タイプ | NCID | |||||
収録物識別子 | AA12038549 | |||||
DOI | ||||||
関連タイプ | isIdenticalTo | |||||
識別子タイプ | DOI | |||||
関連識別子 | info:doi/10.3390/ijms21218041 | |||||
著者版フラグ | ||||||
出版タイプ | VoR | |||||
出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 |