{"created":"2023-05-15T12:05:24.839936+00:00","id":10080,"links":{},"metadata":{"_buckets":{"deposit":"23a6f2ea-3161-4d83-b025-be3219559651"},"_deposit":{"created_by":3,"id":"10080","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"10080"},"status":"published"},"_oai":{"id":"oai:iwate-u.repo.nii.ac.jp:00010080","sets":["1515:1519"]},"author_link":["62527","62525","62528","62526"],"item_16_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2010-12-15","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"24","bibliographicPageEnd":"8301","bibliographicPageStart":"8297","bibliographicVolumeNumber":"195","bibliographic_titles":[{"bibliographic_title":"Journal of Power Sources"}]}]},"item_16_date_6":{"attribute_name":"登録日","attribute_value_mlt":[{"subitem_date_issued_datetime":"2011-09-22"}]},"item_16_description_12":{"attribute_name":"Abstract","attribute_value_mlt":[{"subitem_description":"Aluminum was studied as a current collector for rechargeable lithium batteries to understand electrochemical and passivation behavior. Electrochemical polarization tests, in situ scratch polarization tests and time-of-flight secondary ion mass spectroscopy (ToF-SIMS) analysis in lithium bis-oxalato borate (LiBOB)-containing alkyl carbonate solution were conducted. The Al foil did not follow the alloy and de-alloy process with the LiBOB salt in electrolyte at 0 V vs. Li/Li+ in the cathodic sweep. During the anodic scan to the noble direction, the absence of an oxidation peak up to 3 V vs. Li/Li+ indicated that the air-formed oxide layer of Al was not reduced to metal. Oxide-free Al surfaces made by the in situ scratch test during the electrochemical polarization resulted in abrupt alloy formation with Li at 0 V vs. Li/Li+, but the newly formed surface formed passive films at higher potential with oxygen, namely, Al–O compound, as confirmed by ToF-SIMS.","subitem_description_type":"Other"}]},"item_16_publisher_14":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Elsevier B.V."}]},"item_16_relation_26":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"10.1016/j.jpowsour.2010.07.027","subitem_relation_type_select":"DOI"}}]},"item_16_rights_18":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"Copyright © 2010 Elsevier B.V."}]},"item_16_source_id_9":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"0378-7753","subitem_source_identifier_type":"ISSN"}]},"item_16_text_4":{"attribute_name":"著者(機関)","attribute_value_mlt":[{"subitem_text_value":"Department of Chemical Engineering, Iwate University"},{"subitem_text_value":"Department of Chemical Engineering, Iwate University"},{"subitem_text_value":"Department of Energy Engineering, Hanyang University"},{"subitem_text_value":"Department of Chemical Engineering, Iwate University"}]},"item_16_version_type_27":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Myung, Seung-Taek"}],"nameIdentifiers":[{"nameIdentifier":"62525","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Natsui, Hiroshi"}],"nameIdentifiers":[{"nameIdentifier":"62526","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Sun, Yang-Kook"}],"nameIdentifiers":[{"nameIdentifier":"62527","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Yashiro, Hitoshi"}],"nameIdentifiers":[{"nameIdentifier":"62528","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2016-11-14"}],"displaytype":"detail","filename":"jps-v195i24p8297-8301.pdf","filesize":[{"value":"590.5 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"jps-v195i24p8297-8301.pdf","url":"https://iwate-u.repo.nii.ac.jp/record/10080/files/jps-v195i24p8297-8301.pdf"},"version_id":"95bc50a5-f77b-428a-8be8-3f573886b047"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"Al","subitem_subject_scheme":"Other"},{"subitem_subject":"Current collector","subitem_subject_scheme":"Other"},{"subitem_subject":"Passivation","subitem_subject_scheme":"Other"},{"subitem_subject":"LiBOB","subitem_subject_scheme":"Other"},{"subitem_subject":"Lithium","subitem_subject_scheme":"Other"},{"subitem_subject":"Battery","subitem_subject_scheme":"Other"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Electrochemical behavior of Al in a non-aqueous alkyl carbonate solution containing LiBOB salt","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Electrochemical behavior of Al in a non-aqueous alkyl carbonate solution containing LiBOB salt"}]},"item_type_id":"16","owner":"3","path":["1519"],"pubdate":{"attribute_name":"公開日","attribute_value":"2011-09-22"},"publish_date":"2011-09-22","publish_status":"0","recid":"10080","relation_version_is_last":true,"title":["Electrochemical behavior of Al in a non-aqueous alkyl carbonate solution containing LiBOB salt"],"weko_creator_id":"3","weko_shared_id":-1},"updated":"2023-05-16T11:47:27.848380+00:00"}