| Item type |
学術雑誌論文 / Journal Article(1) |
| 公開日 |
2011-09-22 |
| タイトル |
|
|
タイトル |
Influence of the binder types on the electrochemical characteristics of natural graphite electrode in room-temperature ionic liquid |
| キーワード |
|
|
主題Scheme |
Other |
|
主題 |
Graphite |
| キーワード |
|
|
主題Scheme |
Other |
|
主題 |
Negative electrode |
| キーワード |
|
|
主題Scheme |
Other |
|
主題 |
Lithium-ion battery |
| キーワード |
|
|
主題Scheme |
Other |
|
主題 |
Ionic liquid |
| キーワード |
|
|
主題Scheme |
Other |
|
主題 |
Polyacrylic acid |
| キーワード |
|
|
主題Scheme |
Other |
|
主題 |
Binder |
| 資源タイプ |
|
|
資源タイプ識別子 |
http://purl.org/coar/resource_type/c_6501 |
|
資源タイプ |
journal article |
| 著者 |
宇井, 幸一
十和田, 潤
我妻, 翔
熊谷, 直昭
山本, 圭吾
春山, 洋志
竹内, 謙
小浦, 延幸
|
| 著者別名 |
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|
|
識別子Scheme |
WEKO |
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|
識別子 |
62542 |
|
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姓名 |
Ui, Koichi |
| 著者別名 |
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|
識別子Scheme |
WEKO |
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識別子 |
62543 |
|
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姓名 |
Towada, Jun |
| 著者別名 |
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識別子Scheme |
WEKO |
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識別子 |
62544 |
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姓名 |
Agatsuma, Sho |
| 著者別名 |
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識別子Scheme |
WEKO |
|
|
識別子 |
62545 |
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姓名 |
Kumagai, Naoaki |
| 著者別名 |
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識別子Scheme |
WEKO |
|
|
識別子 |
62546 |
|
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姓名 |
Yamamoto, Keigo |
| 著者別名 |
|
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|
識別子Scheme |
WEKO |
|
|
識別子 |
62547 |
|
|
姓名 |
Haruyama, Hiroshi |
| 著者別名 |
|
|
|
識別子Scheme |
WEKO |
|
|
識別子 |
62548 |
|
|
姓名 |
Takeuchi, Ken |
| 著者別名 |
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|
識別子Scheme |
WEKO |
|
|
識別子 |
62549 |
|
|
姓名 |
Koura, Nobuyuki |
| 著者(機関) |
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|
値 |
Department of Frontier Materials and Functional Engineering, Graduate School of Engineering, Iwate University |
| 著者(機関) |
|
|
値 |
Department of Frontier Materials and Functional Engineering, Graduate School of Engineering, Iwate University |
| 著者(機関) |
|
|
値 |
Department of Frontier Materials and Functional Engineering, Graduate School of Engineering, Iwate University |
| 著者(機関) |
|
|
値 |
Department of Frontier Materials and Functional Engineering, Graduate School of Engineering, Iwate University |
| 著者(機関) |
|
|
値 |
Faculty of Science and Technology, Tokyo University of Science |
| 著者(機関) |
|
|
値 |
Faculty of Science and Technology, Tokyo University of Science |
| 著者(機関) |
|
|
値 |
Faculty of Industrial Science and Technology, Tokyo University of Science |
| 著者(機関) |
|
|
値 |
Faculty of Science and Technology, Tokyo University of Science |
| 登録日 |
|
|
日付 |
2011-09-22 |
| 書誌情報 |
Journal of Power Sources
巻 196,
号 8,
p. 3900-3905,
発行日 2011-04-15
|
| ISSN |
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収録物識別子タイプ |
ISSN |
|
収録物識別子 |
0378-7753 |
| Abstract |
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|
内容記述タイプ |
Other |
|
内容記述 |
To improve the electrochemical characteristics of the natural graphite (NG-3) negative electrode in the LiCl saturated AlCl3-1-ethyl-3-methylimizadolium chloride + thionyl chloride (SOCl2) melt as the electrolyte for non-flammable lithium-ion batteries, we examined the influence of the binder types on its electrochemical characteristics. The cyclic voltammograms showed that the reduction current at 1.2–3.2 V vs. Li/Li(I) was repressed using polyacrylic acid (PAA) as the binder. The charge–discharge tests showed that the discharge capacity and the charge–discharge efficiency of the NG-3 electrode coated with the PAA binder at the 1st cycle were 322.8 mAh g−1 and 65.6%, respectively. Compared with the NG-3 electrode using the conventional poly(vinylidene fluoride) binder, it showed considerably a better cyclability with the discharge capacity of 302.1 mAh g−1 at the 50th cycle. Li(I) ion intercalation into the graphite layers could be improved because the NG-3 electrode coated with the PAA binder changed to a golden-yellow color after the 1st charging, and the formation of first stage LiC6 was demonstrated by X-ray diffraction (XRD) measurement. In addition, the XRD and X-ray photoelectron spectroscopy indicated that one of the side reactions during charging was the formation of LiCl on the graphite surface regardless of the binder types. |
| 出版者 |
|
|
出版者 |
Elsevier B.V. |
| 権利 |
|
|
権利情報 |
Copyright © 2010 Elsevier B.V. |
| DOI |
|
|
関連タイプ |
isVersionOf |
|
|
識別子タイプ |
DOI |
|
|
関連識別子 |
10.1016/j.jpowsour.2010.12.007 |
| 著者版フラグ |
|
|
出版タイプ |
AM |
|
出版タイプResource |
http://purl.org/coar/version/c_ab4af688f83e57aa |
jps-v196i8p3900-3905.pdf (1.1 MB)
