{"created":"2023-05-15T12:09:22.768000+00:00","id":14924,"links":{},"metadata":{"_buckets":{"deposit":"48ebccae-8540-4341-b1f0-7ee2af0c7b40"},"_deposit":{"created_by":19,"id":"14924","owners":[19],"pid":{"revision_id":0,"type":"depid","value":"14924"},"status":"published"},"_oai":{"id":"oai:iwate-u.repo.nii.ac.jp:00014924","sets":["1515:1519"]},"author_link":["84981","84980","84979"],"item_16_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2020-02-01","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"2","bibliographicPageEnd":"13","bibliographicPageStart":"1","bibliographicVolumeNumber":"15","bibliographic_titles":[{"bibliographic_title":"Natural Product Communications"}]}]},"item_16_date_6":{"attribute_name":"登録日","attribute_value_mlt":[{"subitem_date_issued_datetime":"2020-03-26"}]},"item_16_description_12":{"attribute_name":"Abstract","attribute_value_mlt":[{"subitem_description":"Reaction of d-camphor p-toluenesulfonylhydrazone with t-butoxide and elemental selenium in dimethylformamide at an elevated temperature afforded a stable compound having a unique 1,6,6αλ⁴-triselenapentalene ring and 4H-selenopyran-4-selones along with dialkenyl diselenide, dibornylenes, and 1,2,5-triselenepin, and the structural confirmation of these products were carried out by X-ray crystallographic analysis. The sterically crowded 1,6,6aλ⁴-triselenapentalene ring fused with two bornane sleketons was stable enough under aerobic exposure and was inactive toward sodium borohydride reduction but was converted into 1,2-diselenole derivative through m-chloroperbenzoic acid oxidation.","subitem_description_type":"Other"}]},"item_16_publisher_14":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"SAGE"}]},"item_16_relation_26":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isIdenticalTo","subitem_relation_type_id":{"subitem_relation_type_id_text":"info:doi/10.1177/1934578X19896686","subitem_relation_type_select":"DOI"}}]},"item_16_rights_18":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"©The Author(s) 2019"},{"subitem_rights":"Creative Commons Non Commercial CC BY-NC: This article is distributed under the terms of the Creative Commons Attribution-NonCommercial 4.0 License (http:// creativecommons. org/ licenses/ by- nc/ 4. 0/) which permits non-commercial use, reproduction and distribution of the work without further permission provided the original work is attributed as specified on the SAGE and Open Access pages (https:// us. sagepub. com/ en- us/ nam/ open- access- at- sage)."}]},"item_16_source_id_9":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"1934578X","subitem_source_identifier_type":"ISSN"},{"subitem_source_identifier":"15559475","subitem_source_identifier_type":"ISSN"}]},"item_16_text_4":{"attribute_name":"著者(機関)","attribute_value_mlt":[{"subitem_text_value":"Department of Chemistry and Biosciences, Faculty of Science and Engineering, Iwate University"},{"subitem_text_value":"Department of Chemistry and Biosciences, Faculty of Science and Engineering, Iwate University"},{"subitem_text_value":"Department of Chemistry and Biosciences, Faculty of Science and Engineering, Iwate University"}]},"item_16_version_type_27":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"SHIMADA, Kazuaki"}],"nameIdentifiers":[{"nameIdentifier":"84979","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"AOYAGI, Shigenobu"}],"nameIdentifiers":[{"nameIdentifier":"84980","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"TAKIKAWA, Yuji"}],"nameIdentifiers":[{"nameIdentifier":"84981","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2020-03-26"}],"displaytype":"detail","filename":"npc-v15n2p1-13.pdf","filesize":[{"value":"944.1 kB"}],"format":"application/pdf","licensetype":"license_9","mimetype":"application/pdf","url":{"label":"npc-v15n2p1-13","url":"https://iwate-u.repo.nii.ac.jp/record/14924/files/npc-v15n2p1-13.pdf"},"version_id":"39069571-1cf5-40ea-9e98-f7b0ac2414c2"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"d-camphorp-toluenesulfonylhydrazone","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"1,6,6αλ⁴-triselenapentalene","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"4H-selenopyran-4-selone","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"steric protection","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"1,2-diselenole","subitem_subject_language":"en","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Formation of a Sterically Crowded 1,6,6αλ⁴-Triselenapentalene and 4H-Selenopyran-4-selones Fused with Two Bornane Skeletons Through the Reaction of d-Camphor p-Toluenesulfonylhydrazone With a Base and Elemental Selenium","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Formation of a Sterically Crowded 1,6,6αλ⁴-Triselenapentalene and 4H-Selenopyran-4-selones Fused with Two Bornane Skeletons Through the Reaction of d-Camphor p-Toluenesulfonylhydrazone With a Base and Elemental Selenium"}]},"item_type_id":"16","owner":"19","path":["1519"],"pubdate":{"attribute_name":"公開日","attribute_value":"2020-03-26"},"publish_date":"2020-03-26","publish_status":"0","recid":"14924","relation_version_is_last":true,"title":["Formation of a Sterically Crowded 1,6,6αλ⁴-Triselenapentalene and 4H-Selenopyran-4-selones Fused with Two Bornane Skeletons Through the Reaction of d-Camphor p-Toluenesulfonylhydrazone With a Base and Elemental Selenium"],"weko_creator_id":"19","weko_shared_id":-1},"updated":"2023-05-15T14:27:57.683964+00:00"}