| Item type |
学術雑誌論文 / Journal Article(1) |
| 公開日 |
2021-12-14 |
| タイトル |
|
|
タイトル |
Bond cleavage of lignin model compounds into aromatic monomers using supported metal catalysts in supercritical water |
| 言語 |
|
|
言語 |
eng |
| 資源タイプ |
|
|
資源タイプ識別子 |
http://purl.org/coar/resource_type/c_6501 |
|
資源タイプ |
journal article |
| 著者 |
YAMAGUCHI, Aritomo
MIMURA, Naoki
SHIRAI, Masayuki
SATO, Osamu
|
| 著者(機関) |
|
|
値 |
Research Institute for Chemical Process Technology, National Institute of Advanced Industrial Science and Technology (AIST), JST, PRESTO |
| 著者(機関) |
|
|
値 |
Research Institute for Chemical Process Technology, National Institute of Advanced Industrial Science and Technology (AIST) |
| 著者(機関) |
|
|
値 |
Research Institute for Chemical Process Technology, National Institute of Advanced Industrial Science and Technology (AIST), Department of Chemistry and Biological Sciences, Faculty of Science and Engineering, Iwate University |
| 著者(機関) |
|
|
値 |
Research Institute for Chemical Process Technology, National Institute of Advanced Industrial Science and Technology (AIST) |
| 登録日 |
|
|
日付 |
2021-12-14 |
| 書誌情報 |
Scientific Reports
巻 7,
p. 46172,
発行日 2017-04-07
|
| ISSN |
|
|
収録物識別子タイプ |
ISSN |
|
収録物識別子 |
20452322 |
| 抄録 |
|
|
内容記述タイプ |
Abstract |
|
内容記述 |
More efficient use of lignin carbon is necessary for carbon-efficient utilization of lignocellulosic biomass. Conversion of lignin into valuable aromatic compounds requires the cleavage of C–O ether bonds and C–C bonds between lignin monomer units. The catalytic cleavage of C–O bonds is still challenging, and cleavage of C–C bonds is even more difficult. Here, we report cleavage of the aromatic C–O bonds in lignin model compounds using supported metal catalysts in supercritical water without adding hydrogen gas and without causing hydrogenation of the aromatic rings. The cleavage of the C–C bond in bibenzyl was also achieved with Rh/C as a catalyst. Use of this technique may greatly facilitate the conversion of lignin into valuable aromatic compounds. |
| 出版者 |
|
|
出版者 |
Springer Nature |
| 関係URI |
|
|
|
識別子タイプ |
URI |
|
|
関連識別子 |
https://www.nature.com/articles/srep46172 |
|
|
関連名称 |
Bond cleavage of lignin model compounds into aromatic monomers using supported metal catalysts in supercritical water |
| 権利 |
|
|
権利情報 |
© The Author(s) 2017 |
| 権利URI |
|
|
権利情報 |
http://creativecommons.org/licenses/by/4.0/ |
| DOI |
|
|
関連タイプ |
isIdenticalTo |
|
|
識別子タイプ |
DOI |
|
|
関連識別子 |
info:doi/10.1038/srep46172 |
| 著者版フラグ |
|
|
出版タイプ |
VoR |
|
出版タイプResource |
http://purl.org/coar/version/c_970fb48d4fbd8a85 |
sr-v7p46172 (1.7 MB)
