{"created":"2023-05-15T12:09:54.137773+00:00","id":15501,"links":{},"metadata":{"_buckets":{"deposit":"418a24f4-cbaf-4af3-9531-81f2565b3877"},"_deposit":{"created_by":19,"id":"15501","owners":[19],"pid":{"revision_id":0,"type":"depid","value":"15501"},"status":"published"},"_oai":{"id":"oai:iwate-u.repo.nii.ac.jp:00015501","sets":["1515:1519"]},"author_link":["93645","93646","93643","93644"],"item_16_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2020-10-28","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"21","bibliographicPageStart":"8041","bibliographicVolumeNumber":"21","bibliographic_titles":[{"bibliographic_title":"International Journal of Molecular Sciences"}]}]},"item_16_date_6":{"attribute_name":"登録日","attribute_value_mlt":[{"subitem_date_issued_datetime":"2022-01-05"}]},"item_16_description_11":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Vinylene-bridged cyclic boron–difluoride complex of dipyrrin (BODIPY) trimers were successfully prepared from expanded dimethyl-vinylene bridged hexaphyrin(2.1.2.1.2.1) Me-Hex that has the structure of alternate dipyrrins and vinylene bridges. The hexaphyrin(2.1.2.1.2.1) Me-Hex can coordinate with boron ions to a_ord five kinds of cyclic BODIPYs given by step-by-step boron complexations. Crystal structures of all cyclic BODIPYs except for 3BF2-Me-Hex(b) formed non-planar structures. The theoretical calculation predicted that mono-/bis-boron cyclic BODIPYs show the intramolecular charge transfer (ICT) characteristics, whereas tri-boron cyclic BODIPYs have no ICT characteristics. Reflecting these electronic properties, tri-boron cyclic BODIPYs exhibit weak fluorescence in the red region, but mono-/bis-boron cyclic BODIPYs exhibit no emission. Vinylene bridged cyclic dipyrrin trimer Me-Hex is the novel porphyrinoid ligand allowed to control the boron coordination under di_erent reaction conditions to form various boron complexes.","subitem_description_type":"Abstract"}]},"item_16_link_13":{"attribute_name":"抄録（URL）","attribute_value_mlt":[{"subitem_link_text":"Vinylene-Bridged Cyclic Dipyrrin and BODIPY Trimers","subitem_link_url":"https://www.mdpi.com/1422-0067/21/21/8041"}]},"item_16_publisher_14":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"MDPI"}]},"item_16_relation_26":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isIdenticalTo","subitem_relation_type_id":{"subitem_relation_type_id_text":"info:doi/10.3390/ijms21218041","subitem_relation_type_select":"DOI"}}]},"item_16_rights_18":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"© 2020 by the authors. Licensee MDPI, Basel, Switzerland."}]},"item_16_rights_19":{"attribute_name":"権利URI","attribute_value_mlt":[{"subitem_rights":"http://creativecommons.org/licenses/by/4.0/"}]},"item_16_source_id_25":{"attribute_name":"NCID","attribute_value_mlt":[{"subitem_source_identifier":"AA12038549","subitem_source_identifier_type":"NCID"}]},"item_16_source_id_9":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"14220067","subitem_source_identifier_type":"ISSN"}]},"item_16_text_4":{"attribute_name":"著者(機関)","attribute_value_mlt":[{"subitem_text_value":"School of Chemistry and Chemical Engineering, Jiangsu University"},{"subitem_text_value":"Faculty of Science and Engineering, Iwate University"},{"subitem_text_value":"Division of Materials Science, Nara Institute of Science and Technology"},{"subitem_text_value":"Division of Materials Science, Nara Institute of Science and Technology"}]},"item_16_version_type_27":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"XUE, Songlin"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"KUZUHARA, Daiki"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"ARATANI, Naoki"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"YAMADA, Hiroko"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2022-01-05"}],"displaytype":"detail","filename":"ijms-v21n21p8041.pdf","filesize":[{"value":"4.7 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"ijms-v21n21p8041","url":"https://iwate-u.repo.nii.ac.jp/record/15501/files/ijms-v21n21p8041.pdf"},"version_id":"cef91e32-ba5c-48d9-ae91-9ad38e20777a"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"expanded porphyrin","subitem_subject_scheme":"Other"},{"subitem_subject":"boron complex","subitem_subject_scheme":"Other"},{"subitem_subject":"molecular configuration","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Vinylene-Bridged CyclicDipyrrin and BODIPY Trimers","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Vinylene-Bridged CyclicDipyrrin and BODIPY Trimers"}]},"item_type_id":"16","owner":"19","path":["1519"],"pubdate":{"attribute_name":"公開日","attribute_value":"2022-01-05"},"publish_date":"2022-01-05","publish_status":"0","recid":"15501","relation_version_is_last":true,"title":["Vinylene-Bridged CyclicDipyrrin and BODIPY Trimers"],"weko_creator_id":"19","weko_shared_id":-1},"updated":"2023-05-15T13:02:51.481777+00:00"}