{"created":"2024-04-12T01:23:07.853518+00:00","id":2000265,"links":{},"metadata":{"_buckets":{"deposit":"382a175b-cea1-4c63-81c7-13017d9e00c7"},"_deposit":{"created_by":19,"id":"2000265","owner":"19","owners":[19],"pid":{"revision_id":0,"type":"depid","value":"2000265"},"status":"published"},"_oai":{"id":"oai:iwate-u.repo.nii.ac.jp:02000265","sets":["1515:1519"]},"author_link":[],"control_number":"2000265","item_16_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2024-04-01","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"4","bibliographicNumberOfPages":"5","bibliographicPageStart":"043010","bibliographicVolumeNumber":"92","bibliographic_titles":[{"bibliographic_title":"Electrochemistry","bibliographic_titleLang":"en"}]}]},"item_16_date_6":{"attribute_name":"登録日","attribute_value_mlt":[{"subitem_date_issued_datetime":"2024-04-12","subitem_date_issued_type":"Created"}]},"item_16_description_11":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"We fabricated lithium-air secondary batteries (LABs) employing amidebased ionic liquids (ILs) as electrolytes and evaluated their electrochemical characteristics. Lithium bis (trifluoromethanesulfonyl)-amide (Li-TFSA) was employed as the lithium salt, N-methyl-N-propylpyrrolidinium-TFSA (Py13 system) with a cyclic aliphatic cation in the ILs, and N, N-diethyl-N-methyl-N-(2-methoxyethyl)ammonium-TFSA (DEME system) with an acyclic aliphatic cation. The constant-current discharge-charge tests with the capacity controlled at 200mAh (g-carbon)−1 showed that the overvoltage of the LABs using the Py13 system was lower than those of LABs using the DEME system and the organic solvent-based system electrolyte. The cycling performance of the DEME system rapidly decreased at the 74th cycle, while the Py13 system showed 200mAh (g-carbon)−1 up to the 100th cycle, indicating a high stability. Electrochemical impedance measurements showed that the LABs using the Py13 system had the lowest interfacial resistance after the 1st charge. These results indicated that the use of the Py13 system with a relatively high electrical conductivity and low viscosity as the electrolyte would stabilize the cycling performance of the LABs.","subitem_description_language":"en","subitem_description_type":"Abstract"}]},"item_16_publisher_14":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"The Electrochemical Society of Japan","subitem_publisher_language":"en"}]},"item_16_relation_26":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isIdenticalTo","subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.5796/electrochemistry.24-69015","subitem_relation_type_select":"DOI"}}]},"item_16_source_id_9":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"2186-2451","subitem_source_identifier_type":"EISSN"},{"subitem_source_identifier":"1344-3542","subitem_source_identifier_type":"PISSN"}]},"item_16_version_type_27":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_access_right":{"attribute_name":"アクセス権","attribute_value_mlt":[{"subitem_access_right":"open access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_abf2"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorAffiliations":[{"affiliationNames":[{"affiliationName":"Iwate University","affiliationNameLang":"en"}]}],"creatorNames":[{"creatorName":"UI, Koichi","creatorNameLang":"en"}]},{"creatorAffiliations":[{"affiliationNames":[{"affiliationName":"Iwate University","affiliationNameLang":"en"}]}],"creatorNames":[{"creatorName":"NAKAMURA, Sota","creatorNameLang":"en"}]},{"creatorAffiliations":[{"affiliationNames":[{"affiliationName":"Iwate University","affiliationNameLang":"en"}]}],"creatorNames":[{"creatorName":"SATO, Yushi","creatorNameLang":"en"}]},{"creatorAffiliations":[{"affiliationNames":[{"affiliationName":"Iwate University","affiliationNameLang":"en"}]}],"creatorNames":[{"creatorName":"TAKEGUCHI, Tatsuya","creatorNameLang":"en"}]},{"creatorAffiliations":[{"affiliationNames":[{"affiliationName":"Tokyo University of Science","affiliationNameLang":"en"}]}],"creatorNames":[{"creatorName":"ITAGAKI, Masayuki","creatorNameLang":"en"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_access","date":[{"dateType":"Available","dateValue":"2024-04-12"}],"filename":"ec-v92i4p043010.pdf","filesize":[{"value":"1.2 MB"}],"format":"application/pdf","mimetype":"application/pdf","url":{"label":"ec-v92i4p043010.pdf","objectType":"fulltext","url":"https://iwate-u.repo.nii.ac.jp/record/2000265/files/ec-v92i4p043010.pdf"},"version_id":"1a72d412-da3e-4122-a126-fcff1256522c"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"Ionic Liquid","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"Lithium-air Secondary Battery","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"Air-electrode","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"Interfacial Behavior","subitem_subject_language":"en","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Electrochemical Characteristics of Lithium-Air Secondary Battery Using Amide-Based Ionic Liquids","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Electrochemical Characteristics of Lithium-Air Secondary Battery Using Amide-Based Ionic Liquids","subitem_title_language":"en"}]},"item_type_id":"16","owner":"19","path":["1519"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2024-04-12"},"publish_date":"2024-04-12","publish_status":"0","recid":"2000265","relation_version_is_last":true,"title":["Electrochemical Characteristics of Lithium-Air Secondary Battery Using Amide-Based Ionic Liquids"],"weko_creator_id":"19","weko_shared_id":-1},"updated":"2024-04-15T01:04:58.335876+00:00"}