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非環状ポリオキシエチレン化合物の錯生成反応と分析化学への応用
https://iwate-u.repo.nii.ac.jp/records/12606
https://iwate-u.repo.nii.ac.jp/records/12606c3bb9a9d-4144-45fa-ae00-b6fb1f086941
| 名前 / ファイル | ライセンス | アクション |
|---|---|---|
bk-v53n11p1239-1255.pdf (2.2 MB)
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| Item type | 学術雑誌論文 / Journal Article(1) | |||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| 公開日 | 2011-10-04 | |||||||||
| タイトル | ||||||||||
| タイトル | 非環状ポリオキシエチレン化合物の錯生成反応と分析化学への応用 | |||||||||
| 言語 | ||||||||||
| 言語 | jpn | |||||||||
| キーワード | ||||||||||
| 主題Scheme | Other | |||||||||
| 主題 | linear polyoxyethylene | |||||||||
| キーワード | ||||||||||
| 主題Scheme | Other | |||||||||
| 主題 | non-cyclic polyether | |||||||||
| キーワード | ||||||||||
| 主題Scheme | Other | |||||||||
| 主題 | ethylene oxide | |||||||||
| キーワード | ||||||||||
| 主題Scheme | Other | |||||||||
| 主題 | complex formation | |||||||||
| キーワード | ||||||||||
| 主題Scheme | Other | |||||||||
| 主題 | solvent extraction | |||||||||
| キーワード | ||||||||||
| 主題Scheme | Other | |||||||||
| 主題 | ion-pair extraction | |||||||||
| キーワード | ||||||||||
| 主題Scheme | Other | |||||||||
| 主題 | determination of non-ionic surfactant | |||||||||
| キーワード | ||||||||||
| 主題Scheme | Other | |||||||||
| 主題 | alkali and alkaline earth metal ions | |||||||||
| 資源タイプ | ||||||||||
| 資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||||||
| 資源タイプ | journal article | |||||||||
| 著者 |
澤田, 清
× 澤田, 清
× 菊地, 洋一
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| 著者別名 | ||||||||||
| 識別子Scheme | WEKO | |||||||||
| 識別子 | 70174 | |||||||||
| 姓名 | SAWADA, Kiyoshi | |||||||||
| 著者別名 | ||||||||||
| 識別子Scheme | WEKO | |||||||||
| 識別子 | 70175 | |||||||||
| 姓名 | KIKUCHI, Yoichi | |||||||||
| 著者(機関) | ||||||||||
| 値 | 新潟大学理学部 | |||||||||
| 著者(機関) | ||||||||||
| 値 | 岩手大学教育学部 | |||||||||
| 登録日 | ||||||||||
| 日付 | 2011-10-04 | |||||||||
| 書誌情報 |
分析化学 巻 53, 号 11, p. 1239-1255, 発行日 2004-01-01 |
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| ISSN | ||||||||||
| 収録物識別子タイプ | ISSN | |||||||||
| 収録物識別子 | 0525-1931 | |||||||||
| Abstract | ||||||||||
| 内容記述タイプ | Other | |||||||||
| 内容記述 | The complex formation of non-cyclic linear polyoxyethylenes and their alkyl derivatives (POE compounds) and application to analytical chemistry are reviewed. The POE compounds form the complexes with alkali and alkaline earth metal ions in the same manner as the cyclic one (crown ether). Although the selectivity and stability of the complex formation are inferior to that of crown ether, POE compounds are interesting material because they have flexible structure and the compounds having a very long ethylene oxide (EO) unit are available. The structures of the crystalline complexes have been determined as the metal ion is surrounded by EO moieties and similar structures are estimated for the complexes in solution. Generally they form 1 : 1 complexes with a metal ion. In case of long chain POE compounds, however, polynuclear complexes are formed. POE compounds are widely used as non-ionic surfactants (NIS). The complexation of POE compounds has been applied to various separation and determination methods, such as solvent extraction, trace analysis of NIS and metal ions and so on. Peculiar properties of POE compounds as NIS have been also utilized for various analytical methods. | |||||||||
| 出版者 | ||||||||||
| 出版者 | 日本分析化学会 | |||||||||
| その他のタイトル | ||||||||||
| その他のタイトル | Complex formation of non-cyclic polyoxyethylenes and their application to analytical chemistry | |||||||||
| DOI | ||||||||||
| 関連タイプ | isIdenticalTo | |||||||||
| 識別子タイプ | DOI | |||||||||
| 関連識別子 | 10.2116/bunsekikagaku.53.1239 | |||||||||
| 著者版フラグ | ||||||||||
| 出版タイプ | VoR | |||||||||
| 出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||||||
