| Item type |
学術雑誌論文 / Journal Article(1) |
| 公開日 |
2009-01-27 |
| タイトル |
|
|
タイトル |
Magnetic field effects on electrochemical property of self-assembled monolayers with charge-transfer groups |
| キーワード |
|
|
主題Scheme |
Other |
|
主題 |
Electron transfer |
| キーワード |
|
|
主題Scheme |
Other |
|
主題 |
oriented Au(111) surface |
| キーワード |
|
|
主題Scheme |
Other |
|
主題 |
self-assembled monolayers |
| キーワード |
|
|
主題Scheme |
Other |
|
主題 |
superconducting magnet |
| 資源タイプ |
|
|
資源タイプ識別子 |
http://purl.org/coar/resource_type/c_6501 |
|
資源タイプ |
journal article |
| 著者 |
Yoshimoto, Noriyuki
Ogawa, Kaoru
Ogawa, Satoshi
|
| 著者(機関) |
|
|
値 |
Faculty of Engineering, Iwate University |
| 著者(機関) |
|
|
値 |
Iwate Industrial Promotion Center, Advanced Science and Technology Institute of Iwate |
| 登録日 |
|
|
日付 |
2009-01-27 |
| 書誌情報 |
IEEE Transactions on Applied Superconductivity
巻 14,
号 2,
p. 1600-1603,
発行日 2004-01-01
|
| ISSN |
|
|
収録物識別子タイプ |
ISSN |
|
収録物識別子 |
1051-8223 |
| Abstract |
|
|
内容記述タイプ |
Other |
|
内容記述 |
Novel self-organization molecules, n-mercapto-alkyl benzo-annelated tetrathiafulvalenes (BTTF), have been synthesized. Exposure of polycrystalline Au and oriented crystalline Au (111) surfaces to organic solution of the novel BTTF derivatives in high magnetic field results in the binding of the derivatives to Au and the formation of highly-oriented self-assembled monolayers (SAMs) with redox active tetrahia-fulvalene (TTF) unit. The electrochemical properties were confirmed in the monolayer state. A comparison between SAMs on polycrystalline Au having a rough surface andon oriented crystalline Au (111) having a flat surface suggested that the well-oriented alkyl-chain layers in the SAMs could be blockade for the electron transfer between the TTF unit and the Au substrate. |
| 出版者 |
|
|
出版者 |
IEEE |
| 権利 |
|
|
権利情報 |
©IEEE |
| DOI |
|
|
関連タイプ |
isIdenticalTo |
|
|
識別子タイプ |
DOI |
|
|
関連識別子 |
10.1109/TASC.2004.830729 |
| 著者版フラグ |
|
|
出版タイプ |
VoR |
|
出版タイプResource |
http://purl.org/coar/version/c_970fb48d4fbd8a85 |
itas-v14n2p1600-1603.pdf (316.1 kB)
