| Item type |
学術雑誌論文 / Journal Article(1) |
| 公開日 |
2020-03-26 |
| タイトル |
|
|
タイトル |
Formation of a Sterically Crowded 1,6,6αλ⁴-Triselenapentalene and 4H-Selenopyran-4-selones Fused with Two Bornane Skeletons Through the Reaction of d-Camphor p-Toluenesulfonylhydrazone With a Base and Elemental Selenium |
| 言語 |
|
|
言語 |
eng |
| キーワード |
|
|
言語 |
en |
|
主題Scheme |
Other |
|
主題 |
d-camphorp-toluenesulfonylhydrazone |
| キーワード |
|
|
言語 |
en |
|
主題Scheme |
Other |
|
主題 |
1,6,6αλ⁴-triselenapentalene |
| キーワード |
|
|
言語 |
en |
|
主題Scheme |
Other |
|
主題 |
4H-selenopyran-4-selone |
| キーワード |
|
|
言語 |
en |
|
主題Scheme |
Other |
|
主題 |
steric protection |
| キーワード |
|
|
言語 |
en |
|
主題Scheme |
Other |
|
主題 |
1,2-diselenole |
| 資源タイプ |
|
|
資源タイプ識別子 |
http://purl.org/coar/resource_type/c_6501 |
|
資源タイプ |
journal article |
| 著者 |
SHIMADA, Kazuaki
AOYAGI, Shigenobu
TAKIKAWA, Yuji
|
| 著者(機関) |
|
|
値 |
Department of Chemistry and Biosciences, Faculty of Science and Engineering, Iwate University |
| 著者(機関) |
|
|
値 |
Department of Chemistry and Biosciences, Faculty of Science and Engineering, Iwate University |
| 著者(機関) |
|
|
値 |
Department of Chemistry and Biosciences, Faculty of Science and Engineering, Iwate University |
| 登録日 |
|
|
日付 |
2020-03-26 |
| 書誌情報 |
Natural Product Communications
巻 15,
号 2,
p. 1-13,
発行日 2020-02-01
|
| ISSN |
|
|
収録物識別子タイプ |
ISSN |
|
収録物識別子 |
1934578X |
| ISSN |
|
|
収録物識別子タイプ |
ISSN |
|
収録物識別子 |
15559475 |
| Abstract |
|
|
内容記述タイプ |
Other |
|
内容記述 |
Reaction of d-camphor p-toluenesulfonylhydrazone with t-butoxide and elemental selenium in dimethylformamide at an elevated temperature afforded a stable compound having a unique 1,6,6αλ⁴-triselenapentalene ring and 4H-selenopyran-4-selones along with dialkenyl diselenide, dibornylenes, and 1,2,5-triselenepin, and the structural confirmation of these products were carried out by X-ray crystallographic analysis. The sterically crowded 1,6,6aλ⁴-triselenapentalene ring fused with two bornane sleketons was stable enough under aerobic exposure and was inactive toward sodium borohydride reduction but was converted into 1,2-diselenole derivative through m-chloroperbenzoic acid oxidation. |
| 出版者 |
|
|
出版者 |
SAGE |
| 権利 |
|
|
権利情報 |
©The Author(s) 2019 |
| 権利 |
|
|
権利情報 |
Creative Commons Non Commercial CC BY-NC: This article is distributed under the terms of the Creative Commons Attribution-NonCommercial 4.0 License (http:// creativecommons. org/ licenses/ by- nc/ 4. 0/) which permits non-commercial use, reproduction and distribution of the work without further permission provided the original work is attributed as specified on the SAGE and Open Access pages (https:// us. sagepub. com/ en- us/ nam/ open- access- at- sage). |
| DOI |
|
|
関連タイプ |
isIdenticalTo |
|
|
識別子タイプ |
DOI |
|
|
関連識別子 |
info:doi/10.1177/1934578X19896686 |
| 著者版フラグ |
|
|
出版タイプ |
VoR |
|
出版タイプResource |
http://purl.org/coar/version/c_970fb48d4fbd8a85 |
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