| Item type |
学術雑誌論文 / Journal Article(1) |
| 公開日 |
2022-01-05 |
| タイトル |
|
|
タイトル |
Vinylene-Bridged CyclicDipyrrin and BODIPY Trimers |
| 言語 |
|
|
言語 |
eng |
| キーワード |
|
|
主題Scheme |
Other |
|
主題 |
expanded porphyrin |
| キーワード |
|
|
主題Scheme |
Other |
|
主題 |
boron complex |
| キーワード |
|
|
主題Scheme |
Other |
|
主題 |
molecular configuration |
| 資源タイプ |
|
|
資源タイプ識別子 |
http://purl.org/coar/resource_type/c_6501 |
|
資源タイプ |
journal article |
| 著者 |
XUE, Songlin
KUZUHARA, Daiki
ARATANI, Naoki
YAMADA, Hiroko
|
| 著者(機関) |
|
|
値 |
School of Chemistry and Chemical Engineering, Jiangsu University |
| 著者(機関) |
|
|
値 |
Faculty of Science and Engineering, Iwate University |
| 著者(機関) |
|
|
値 |
Division of Materials Science, Nara Institute of Science and Technology |
| 著者(機関) |
|
|
値 |
Division of Materials Science, Nara Institute of Science and Technology |
| 登録日 |
|
|
日付 |
2022-01-05 |
| 書誌情報 |
International Journal of Molecular Sciences
巻 21,
号 21,
p. 8041,
発行日 2020-10-28
|
| ISSN |
|
|
収録物識別子タイプ |
ISSN |
|
収録物識別子 |
14220067 |
| 抄録 |
|
|
内容記述タイプ |
Abstract |
|
内容記述 |
Vinylene-bridged cyclic boron–difluoride complex of dipyrrin (BODIPY) trimers were successfully prepared from expanded dimethyl-vinylene bridged hexaphyrin(2.1.2.1.2.1) Me-Hex that has the structure of alternate dipyrrins and vinylene bridges. The hexaphyrin(2.1.2.1.2.1) Me-Hex can coordinate with boron ions to a_ord five kinds of cyclic BODIPYs given by step-by-step boron complexations. Crystal structures of all cyclic BODIPYs except for 3BF2-Me-Hex(b) formed non-planar structures. The theoretical calculation predicted that mono-/bis-boron cyclic BODIPYs show the intramolecular charge transfer (ICT) characteristics, whereas tri-boron cyclic BODIPYs have no ICT characteristics. Reflecting these electronic properties, tri-boron cyclic BODIPYs exhibit weak fluorescence in the red region, but mono-/bis-boron cyclic BODIPYs exhibit no emission. Vinylene bridged cyclic dipyrrin trimer Me-Hex is the novel porphyrinoid ligand allowed to control the boron coordination under di_erent reaction conditions to form various boron complexes. |
| 抄録（URL） |
|
|
表示名 |
Vinylene-Bridged Cyclic Dipyrrin and BODIPY Trimers |
|
URL |
https://www.mdpi.com/1422-0067/21/21/8041 |
| 出版者 |
|
|
出版者 |
MDPI |
| 権利 |
|
|
権利情報 |
© 2020 by the authors. Licensee MDPI, Basel, Switzerland. |
| 権利URI |
|
|
権利情報 |
http://creativecommons.org/licenses/by/4.0/ |
| NCID |
|
|
収録物識別子タイプ |
NCID |
|
収録物識別子 |
AA12038549 |
| DOI |
|
|
関連タイプ |
isIdenticalTo |
|
|
識別子タイプ |
DOI |
|
|
関連識別子 |
info:doi/10.3390/ijms21218041 |
| 著者版フラグ |
|
|
出版タイプ |
VoR |
|
出版タイプResource |
http://purl.org/coar/version/c_970fb48d4fbd8a85 |
ijms-v21n21p8041 (4.7 MB)
